Preheat your oven to 350°F (175°C). Grease 3 8-inch round cake pans, and line the bottoms with parchment paper.
In a large bowl, whisk together the flour, granulated sugar, brown sugar, cocoa powder, baking soda, baking powder, and salt.
2 cups all-purpose flour, 1 1/3 cups granulated sugar, 1 cup brown sugar, 1 cup cocoa powder, 2 1/2 tsp baking soda, 2 tsp baking powder, 1 tsp salt
In another bowl, whisk together the buttermilk, orange juice, oil, eggs, vanilla extract, and orange zest.
1 1/4 cups buttermilk, 3/4 cup orange juice, 2/3 cup vegetable oil, 3 eggs, 1 tbsp vanilla extract, zest from 1 orange
Add the wet ingredients to the dry ingredients and mix until combined. Make sure there are no pockets of flour but avoid overmixing.
Divide the batter equally between the prepared cake pans. Tap the pans on the countertop to remove any air bubbles. Bake for 25-30 minutes or until a toothpick inserted into the center comes out with a few crumbs.
Remove the cakes from the oven and allow them to cool in the pans for 10 minutes before removing from pans and transferring them to wire racks to cool completely.